(E)-N′-(4-Methoxybenzylidene)pyridine-3-carbohydrazide dihydrate

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(E)-N′-(4-Meth­oxy­benzyl­idene)pyridine-3-carbohydrazide dihydrate

In the title compound, C14H13N3O2·2H2O, the hydrazone mol-ecule adopts an E conformation with respect to the C=N bond. The dihedral angle between the benzene and pyridine rings is 8.55 (10)°. The methyl-idene-hydrazide [-C(=O)-N-N=C-] fragment is essentially planar, with a maximum deviation of 0.0375 (13) Å. The mean planes of the benzene and pyridine rings make dihedral angles of 2.71 (14) and...

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N′-[(E)-4-Hydr­oxy-3-methoxy­benzyl­idene]pyridine-4-carbohydrazide

In the title compound, C(14)H(13)N(3)O(3), the two six-membered rings are oriented at a dihedral angle of 15.17 (11)° and an intra-molecular O-H⋯O hydrogen bond occurs. In the crystal, mol-ecules inter-act by way of N-H⋯O, O-H⋯N and C-H⋯O hydrogen bonds, thereby generating S(5) chain and R(2) (1)(7) ring motifs.

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N′-[(E)-(3-Fluoro­pyridin-2-yl)methyl­idene]pyridine-3-carbohydrazide dihydrate

The organic molecule in the title dihydrate, C12H9FN4O·2H2O, exists in the E conformation with respect to the azo-methane C=N double bond. The mol-ecule is approximately planar, with a maximum deviation of 0.117 (1) Å for the carbonyl O atom from the mean plane of the mol-ecule. Both pyridine rings are essentially coplanar with the central C(=O)N2C unit [dihedral angles = 1.99 (7) and 5.71 (8)°...

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(E)-N′-Benzyl­idene-5-methyl­isoxazole-4-carbohydrazide

The mol-ecule of the title compound, C(12)H(11)N(3)O(2), is approximately planar with an r.m.s. deviation of 0.0814 Å from the plane through all the non-H atoms. The dihedral angle formed by the benzene and isoxazole rings is 6.88 (16)°. The mol-ecular conformation is stabilized by an intra-molecular C-H⋯N hydrogen bond, forming an S(6) ring, and the mol-ecule displays an E configuration with r...

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N′-[(E)-4-Bromo­benzyl­idene]pyrazine-2-carbohydrazide

In the title compound, C12H9BrN4O, the N'-methyl-idene-pyrazine-2-carbohydrazide and 4-bromobenzene groups are oriented at a dihedral angle of 10.57 (7)°. The hydrazide N-H group is involved in intra-molecular N-H⋯N inter-action, which generates an S(5) motif. A short C-H⋯O inter-action is formed between the methyl-idene H atom and the carbonyl O atom. It connects mol-ecules into chains extendi...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2013

ISSN: 1600-5368

DOI: 10.1107/s1600536813017406